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含有萘四甲酸二酰亚胺衍生物的电照相感光体及采用其的电照相成像设备
Electrophotographic photoreceptor containing naphthalenetetracarboxylic acid diimide derivatives and electrophotographic imaging apparatus employing the same
US-7396624-B2用于电照相成像设备,提高电子传输能力。
专利摘要
一种含有式(1)的萘四甲酸二酰亚胺衍生物的电照相感光体,该衍生物具有在相对于酰亚胺基团的氮原子的α位被芳基取代的支链烷基:其中R1和R2独立地选自氢原子、卤素原子、C1-C20取代或未取代的烷基和C1-C20取代或未取代的烷氧基;R3选自C1-C20取代或未取代的烷基、C1-C20取代或未取代的烷氧基、C7-C30取代或未取代的芳烷基和具有式—(CH2)n—Y—R4的基团;Ar是C6-C30取代或未取代的芳基;Y是氧或硫原子;R4是氢原子或C1-C20取代或未取代的烷基;n是1至12之间的整数。该萘四甲酸二酰亚胺衍生物在有机溶剂中具有高溶解度和与粘合剂树脂的相容性,从而提供更好的电子传输能力。本发明还涉及使用该感光体的电照相成像设备。
Original abstractAn electrophotographic photoreceptor containing a naphthalenetetracarboxylic acid diimide derivative of Formula (1), which has a branched alkyl group substituted with an aryl group at the α-position with regard to nitrogen atoms of imide groups: wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a halogen atom, a C 1 -C 20 substituted or unsubstituted alkyl group, and a C 1 -C 20 substituted or unsubstituted alkoxy group; R 3 is selected from the group consisting of a C 1 -C 20 substituted or unsubstituted alkyl group, a C 1 -C 20 substituted or unsubstituted alkoxy group, a C 7 -C 30 substituted or unsubstituted aralkyl group, and a group having the formula —(CH 2 ) n —Y—R 4 ; Ar is a C 6 -C 30 substituted or unsubstituted aryl group; Y is an oxygen or sulfur atom; R 4 is a hydrogen atom or a C 1 -C 20 substituted or unsubstituted alkyl group; and n is an integer between 1 and 12. The naphthalenetetracarboxylic acid diimide derivative has high solubility in organic solvents and compatibility with binder resins, thus providing better electron transporting ability. The invention is also directed to an electrophotographic imaging apparatus using the photoreceptor.
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